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Creators/Authors contains: "Hyun, Sung-Min"

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  1. ; ; ; ; ; ; (, Chemical Communications)
    Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms. 
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  2. ; ; ; ; ; ; ; (, Organometallics)
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  3. ; ; ; ; ; ; ; (, Journal of Chemical Education)
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  4. ; ; ; ; (, Chem)
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  5. ; ; ; ; ; ; ; ; (, Chemical Communications)
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    Temperature-dependent metalation of the new hexadentate ligand (tris(5-(pyridin-2-yl)-1 H -pyrrol-2-yl)methane; H 3 TPM) enables the selective synthesis of both mononuclear ( i.e. Na(THF) 4 [Fe(TPM)], kinetic product) and trinuclear ( i.e. Fe 3 (TPM) 2 , thermodynamic product) complexes. Exposure of Na(THF) 4 [Fe(TPM)] to FeCl 2 or ZnCl 2 triggers cluster expansion to generate homo- or heterometallic trinuclear complexes, respectively. The developed approach enables systematic variation of ion content in isostructural metal clusters via programmed assembly. 
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  6. ; ; ; ; ; (, Inorganic Chemistry)
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